![]() ![]() And the logo of the red horse remains the company’s signature look which symbolizes strength and independence - important tenets of the company’s core values. According to the company, the logo represents Da Ma Cai’s goal of moving forwards in the industry in an unrelenting pursuit of excellence. ![]() Today, the iconic charging horse logo is synonymous with the brand. Since then, this provider has come to be known as one of the biggest names in the 4D market in Malaysia - a prestigious list that also includes the likes of Sports Toto and Magnum 4D. You might have noticed that we did not mention the 4D special draw for GD Lotto and Perdana 4D because their results are drawn every day.Da Ma Cai ( 大马彩 ) was established as the brand identity for Pan Malaysian Pools Sdn. The 4D special draw is applicable to the following lottery operators: The Perikatan Nasional (PN) federal government, which replaced Harapan, apparently restored the number of special draws back to 22.īecause of the 4D special draw, the lottery participants now have a higher chance of winning the lottery. This is very essential in terms of the end result towards the increase in banned betting and service operations of lottery agents.Īs a control measure, the ministry has actually put stringent requirements on licence holders to make sure the gaming industry was maintained correctly, while cooperation with pertinent firms will likewise be heightened to restrain prohibited gambling activities. The Finance Ministry bore in mind the recommendations recommended by Yang Berhormat and is presently assessing the advice on the special draw amounts. The special draw is very important not only considering that it boosts the federal government fund but additionally offer more opportunities for the 4D individuals to win prizes.īased on the latest news in 2023, the federal government will not increase 4D special draws for numbers forecast operators beyond the present ceiling of 22 per year. The amount of "special draws" was increased to 22 again by the present federal government. There were 22 "special draws" in 2018 before being reduced by the Pakatan Harapan authorities to 11 in 2019, and after that eight in 2020. The "special draw" was announced in 1999 under the Barisan Nasional (BN) government to increase funds for victims of the Nipah infection outbreak. The total number of special draws permitted annually now is 22 and among the main factors for this special draw is to raise government finance. Special Draws fall on Tuesday and it is undoubtedly exclusive simply because these draws need to be approved by the Malaysian authorities. It is truly the leading lottery platform in Malaysia. The good news is, GD4D provides you with an easier option for 4D special draw dates because you can view all the special draw dates for all lotteries at a glance.īesides special draw date updates, you can buy 4D online and check the latest 4D results at GD4D. You can easily get the 4D special draw dates on the official lottery operator websites. It is important to get the latest update on the 4D special draw so that you would not miss buying the lottery. On this page, you will find the 4D special draw date for the following: (Tue) Special Draw - 4D Lottery Special Draw (UPDATED) in MalaysiaĪre you looking for the 4D special draw date for 2023? You’re at the right place. ![]()
0 Comments
![]() ![]() For example, -ipdb indicates that the input molecule specification is in PDB format and that the extension. The options specifying the formats of the input and output molecule specifications are formed from the string -i or -o (respectively), followed immediately by the appropriate option form string from the preceding table corresponding to the desired molecule specification format (no spaces intervene). for crystal structures (requires exactly 3 trans. MacroModel data file (may be formatted or unformatted)įractional coords. The default extensions are listed in the following table: Extension In general, extensions can be omitted from file specifications provided that extension conventions are followed. If the output filename is omitted, it is given the same base name as the input file, along with a conventional extension denoting its file type. Where option( s) is one or more options, specifying the desired operations, input-file is the file containing the structure to be converted (or retrieved), and output-file is the file in which to place the new molecule specification (or Gaussian input). Newzmat option( s) input-file output-file Newzmat has the following general syntax: Newzmat can retrieve intermediate structures from a checkpoint file from (or during) a geometry optimization, for reuse or display. This capability can be used to extract data for display with a visualization package. Newzmat can also generate Gaussian 09 checkpoint files from other data files, and (more importantly) generate the data files from checkpoint files. The resulting data files have the proper symmetry constraints for efficient computation (if applicable). newzmat can thus be used to produce Gaussian input from the data files of many popular graphics and mechanics packages, allowing them to act as graphical input front-ends to Gaussian. This includes generating a Z-matrix (and hence input for Gaussian) from the files produced by other programs and also converting between the file formats of any of these programs. Newzmat can convert molecule specifications between a variety of data file formats. Its full set of capabilities includes the following: It can also perform many related functions, such as extracting molecule specifications from Gaussian checkpoint files. The newzmat utility was designed primarily for converting molecule specifications between a variety of standard formats. ![]() ![]() ![]() I'm a vet - this is the one thing dog and cat owners MUST do to protect their animals from harm if they have an artificial lawn. ![]() Devastating double blast at Romanian gas station kills two and injures 56: Pictures show how deadly explosions flattened homes and left crater in floor.Dr MAX PEMBERTON'S lesson from Letby: Rein in NHS bosses who treat doctors as a nuisance.British girl, 11, is killed in horror jet ski crash on holiday in Turkey - as two men, aged 25 and 17 are facing manslaughter charges.Miss you, ma'am: Royals gather for first summer at Balmoral since Queen's death - Charles and Camilla are joined by William, Kate, Andrew, Edward, Sophie and Queen's lady-in-waiting Lady Susan Hussey at church.Horoscope today: Daily guide to what the stars have in store for YOU - August 28, 2023.Missing The Mark! Luxury NYC hotel which hosted Meghan Markle's infamous baby shower is slammed by socialites who 'saw RATS in its caviar restaurant'.but now we're so happy living in our 'forever home' Our DIY SOS nightmare: My family including my disabled son were attacked online by traders after appearing in hit BBC makeover show.Huge crowd gathers at heartbreaking vigil honouring Irish youngsters killed in horror crash after celebrating their exam results.Heartbroken boyfriend of girl, 18, who was killed in horror crash with her brother and two friends tells how he ran to scene after receiving final Snapchat message from her.Are YOU using WhatsApp all wrong? Majority of users are not aware of these 10 game-changing hacks - including how to prevent photo quality from dropping.Chris Packham's sniff of goshawk chick on BBC's The One Show is at centre of police probe over claims that it was a 'disturbance' of a protected species.Notting Hill Carnival 2023 LIVE: Latest updates from west London as thousands celebrate in Europe's biggest street festival.Foreign criminal, 45, who was spared deportation from the UK at 11th hour after protests is arrested on suspicion of rape.Maya Jama and Stormzy confirm their relationship is back ON as couple emerge hand-in-hand during day out in Greece.Ukraine offensive 'will speed up' after its forces broke through Russia's strongest line of defence, top commander claims.'We're ready to use it': Anger at controverisal inventor dubbed 'Dr Death' who says his 3D-printed coffin-like 'suicide capsules' will be used for the first time this YEAR.Star of 'TV's funniest interview' Guy Goma reveals he is SUING the BBC for not paying him for viral clip and insists he could have made millions, as the meme turns seventeen.Revealed: Final tragic steps of mother 'murdered' in Kent while walking her dog as detectives probing her death continue to quiz suspected killer.Bullets that are a haunting testament to brutality of WW2: Mass grave site of German soldiers who were forced to dig their own graves before being shot dead by the French resistance after D-Day is found.Singer Florence Welch, 36, reveals she has had LIFE-SAVING surgery after cancelling gigs and tells fans she is 'not yet strong enough' to detail her ordeal.Hurricane-force gusts batter Majorca as 'extreme' thunderstorms hit island: Several tourists are hurt as terrifying 75mph winds rip into Spanish resort with trees crashing down, streets flooding and holidaymakers forced to run for cover. ![]() ![]() XRECODE3, as its name indicates, is an app for audio files, capable of converting them between more than a dozen formats, some of which have yet to be mentioned. ◆Import/export: Import various audio and video formats, such as MP3, WAV, OGG, WMA, AC3, AAC, AIFF, MP4, MOV, 3GP, 3G2, MPEG, FLV, WTV, AVI, AMV, RM, M4A, MPG, MPG2, DAT, RAM, MP2, RA, TTA, TPE, RV, and VIVO export various formats, such as MP3, WAV, OGG, WMA, AC3, AAC, AIFF, MP4, MOV, 3GP, 3G2, MPEG, FLV, WTV, AVI ◆Video properties: Play, pause, stop, fast-forward, rewind, and adjust volume. ◆Audio properties: Play, pause, stop, fast-forward, rewind, shuffle, repeat, volume control, mute, adjust volume, mute recording, and more. ◆Record & convert: Record from any audio source, such as your computer’s built-in microphone, external microphone, or line-in convert any audio file from one format to another, such as MP3 to WAV create and convert WAV to FLAC, MP3, WMA, OGG, AC3, AAC, and AIFF merge multiple audio files into one file extract audio from video files to convert into WAV, MP3, WMA, OGG, AC3, AAC, and AIFF perform batch conversion of multiple audio and video files store all your audio files in different folders and use them at any time combine multiple audio and video files into one file extract audio from video files to convert into WAV, MP3, WMA, OGG, AC3, AAC, and AIFF process multiple audio and video files add many audio and video effects, such as fade in and out load favorite audio and video clips to the clipboard create playlist and more. KEYMACRO can perform the following functions: ![]() It can also be used to record audio from any audio source and convert it into multiple formats, such as WAV, MP3, FLAC, OGG, AC3, AAC, and AIFF. KEYMACRO is a powerful multilingual audio recorder that allows you to record, combine, and convert audio and video files easily, so you can easily make high-quality, professional-looking videos with your keyboard. XRECODE3 Crack Free Registration Code For Windows Latest The music library can hold over 500,000 audio files that you can browse through by artist, album, genre, etc. And did we mention that the app is free? This app deserves a place in your toolkit. ![]() With a simple, elegant interface, users can browse through their music library, create playlists, play and edit their own audio recordings, and more. Wavesurfer is a music player and recording studio for your iPhone, iPod, and iPad. ?Media Player/Drive and Media Library windows ❤For information about new version update, please kindly check our site(✅Screenshots ![]() ✔Option to enable live preview in MP3 format. ✔Ability to process multiple files at once. ✔Option to modify the artwork, if you like. ✔Option to add smart bookmarking to your converted songs. ✔Option to preserve the original folder structure. ✔Improved CD ripping function: Now you can easily rip CD songs without the help of third-party apps. The most popular codecs in the world are supported by XRECODE: MP3, M4A, FLAC, WAV, OGG, AAC, APE, and more. Thanks to XRECODE’s advanced technology, it can automatically detect the audio format of any audio file. ![]() With this program, you can easily convert any audio file you need: just pick the source file(s) and let XRECODE3 handle the conversion process itself. In just a few easy steps, you can convert any type of audio files to any format, such as: MP3, M4A, FLAC, MP4, AVI, and many others. Convert songs and audio recordings in just a couple of clicks! ![]() ![]() ![]() Please show your love and support by sharing this post. Git comes with built-in GUI tools (git-gui, gitk), but there are several third-party tools for users looking for a platform-specific experience.
![]() ![]() The Senate on Saturday acquitted Donald Trump of inciting the attack on the U.S. Former President Donald Trump’s Mar-a-Lago resort where he resides after leaving the White House on Februin Palm Beach, Florida. Neither Place of Hope, Big Dog Ranch Rescue, nor Mar-a-Lago responded to The Daily Beast’s request for comment about precautions taken. Former President Donald Trumps Palm Beach club has been partially closed because of a COVID outbreak. COVID-19 outbreak at Trumps Mar-a-Lago club leads to partial closure, per report. The events, complete with dog shows and an auction, reportedly raised $1.4 million. The Florida resort has served as the former. In one video from the event posted by Miami philanthropist Angela Bird, a topless male model walked down a catwalk as mask-less woman screamed and cheered at nearby tables. Donald Trump's main residence, Mar-a-Lago, has been partially closed after some staff members tested positive for Covid-19, US media report. Usually the annual gala- almost always held at Trump properties-attracts at least 800 people, but, due to COVID-19, organizers split the event into two bashes of about 500 people across two days.Īved insisted everyone wore masks and tried their best to social distance-“maybe not six feet, but at least three feet apart”-in the Grand Ballroom.īut dozens of photos and videos from the event show almost no attendees wearing masks, and women screaming and crowding around one another to take photos. Trump was spotted entertaining guests at his Mar-A-Lago club on Tuesday.It comes days after a COVID outbreak forced the club partially to close. She was at Mar-a-Lago last week during two wild fundraiser events put on for a dog charity, Big Dog Ranch Rescue, chaired by Donald Trump’s daughter-in-law Lara Trump. Former President Donald Trumps Mar-a-Lago resort has partially shut down due to a Covid-19. A post shared by Valentina Deva who goes by Valentina Deva on Instagram, told The Daily Beast that two kitchen staff members had tested positive. ![]() ![]() ![]() ![]() ![]() Supply Sergeant for a 42 Soldier Signal Company responsible for maintaining Global Combat Support System-Army (GCSS-A), to include the ordering and reconciliation of all supplies and equipment tracking of the unit logistics budget monitoring the pick-up and turn in of all equipment coming to and leaving the unit management and tracking of transportation, ammunition, billeting, inventories, load plans, licensing, field preparation and return. Serves as the Supply Noncommissioned Officer of the most geographically-dispersed recruiting battalion in USAREC, consisting of 6 time zones, 199 Soldiers, 27 DA Civilians, 4 contractors, 5 recruiting companies, 34 recruiting centers, a battalion headquarters elements, and 2 MEPS responsible for the request, receipt, issue, and accountability of individual, organizational, installation, and expendable supplies and equipment assists in property accountability, ensuring total accuracy ensures critical assets were on hand or ordered monitors all sensitive items and unit inventories initiated Financial Liability Investigations of Property Loss (FLIPL) accounts for the health, personal welfare, and training of three Soldiers and directly responsible for $10 million worth of organizational equipment. Responsible for the training and personal welfare of four Soldiers. Support (GCSS-Army) system assists and advises the Executive Officer and Troop Commander on logistical matters Property books and transaction files initiates financial liability investigations of property loss (FLIPL) responsible for over $12 million worth of organizational equipment maintains property accountability within the global combat Performs preventive and organizational maintenance on weapons and other sensitive items oversees transactions to Unit Supply Sergeant assigned to a Dismounted Reconnaissance Troop responsible for the request, receipt, issue, andĪccountability, of individual, organizational, installation, and expendable supplies and equipment schedules and Senior supply NCO for the Joint Forces Headquarters Logistical Support Center (LSC) functions as the unit, battalion, and brigade level 92Y works directly with other MSCs and state logisticians responsible for $19M of unit property, managing 60 storage locations in Global Combat Service Support-Army (GCSS-A), and supervising two subordinate unit supply NCOs oversees the day-to-day supply operations, requesting, receiving, hand receipting, and turn-in of all Non-Expendable, Expendable and Durable items, Government Purchase Card (GPC) purchases, Soldier Organizational Clothing and Individual Equipment (OCIE) and Central Clothing Distribution Center (CCDF) transactions. ![]() ![]() ![]() ![]() De La Salle University Hideaki Kasai Osaka University Abstract We explore the initial driving. A free energy correlation supports this conclusion. Initial driving force for proton transfer in Nafion Authors: Muneyuki Tsuda Nelson B. These are ascribed to a strong coupling of the electron transfer with the concomitant, thermodynamically favorable proton transfer. Comparisons with rates calculated with the use of Marcus theory reveal that reactions of +, where the electron transfer product is the highly acidic 2+, show rate enhancements of several orders of magnitude. Rate-Driving Force Relationships in the Multisite Proton-Coupled Electron Transfer Activation of Ketones J Am Chem Soc. A free energy correlation supports this conclusion.ĪB - The rates of reduction of the nickel(III) oxime-imine complexes, + and 2+ by the corresponding iron(II) species are determined. In addition to increasing the driving force for proton transfer, enhancing the basicity of the carboxylate also decreases the equilibrium proton donor-acceptor. Here we present a detailed kinetic study of the multisite proton-coupled electron transfer (MS-PCET) activations of aryl ketones using a variety of Brønsted acids and excited-state Ir. Comparisons with rates calculated with the use of Marcus theory reveal that reactions of +, where the electron transfer product is the highly acidic 2+, show rate enhancements of several orders of magnitude. The rate dependence on the driving force for both electron transfer and proton transfer-employing different combinations of oxidants and bases-was used to establish experimentally the concerted. N2 - The rates of reduction of the nickel(III) oxime-imine complexes, + and 2+ by the corresponding iron(II) species are determined. Understanding proton transfer in nanochannels on the molecular level remains a fundamental issue in various areas of science and technology, from biological systems to electrochemical energy conversion 1, 2, 3. In each catalytic cycle, four pumped protons are transferred from the N-side to the P-side of the membrane. ![]() The authors thank CAPES (Brazil) for a maintenance grant to M.C.M.L. Different redox states of the metal centers formed by electron transfer provide the driving force for proton pumping. electrodes reveal unusual reaction rate / driving force effects that are. T1 - Driving force effects in proton coupled electron transfer EVALUATING INTERFACIAL CHARGE TRANSFER KINETICS AND ENERGETICS VIA LASER BASED. ![]() ![]() ![]() ![]() The antivirus should provide both continuous protection and on-demand protection against malicious software.įeaturing an on-demand scanner, "always on" real-time protection, and a continuously updated database of known malware, Comodo Antivirus provides superior protection against zero-day malware and other threats that your Mac may face. Mac users should install an antivirus software that can keep them protected even if there is a vulnerability in their Mac’s built-in security software. Because of this, it is prudent to install additional protection on your Mac in the form of antivirus software from a trusted provider. But recent studies have suggested that Mac malware is seeing enormous growth, and although Apple has increased security features and introduced Gatekeeper, which blocks unapproved software from running on your Mac without your agreement, Mac security features have been bypassed. Historically Macs have been considered safer than Windows PCs, and many Mac users have done without an antivirus software. Malware Protection for Mac Devices Do I Need Antivirus for Mac? Comodo Mobile Security for iPhone has all these features and more, and is available for free. Mobile security apps can ensure greater protection than the iPhone affords on its own, through features like hacked account alerts, identity theft protection, password management, safe browsing, and backups. This is a major advantage Apple has over its competitors as far as security is concerned, as evidenced by the issues the Google Play Store has seen with fake, malware-containing apps.ĭespite this fact, iPhone users would be wise to add additional security to their phones through a mobile security app. Because of this, the chances of one of these apps containing malware is very slim. Importance of Using Antivirus for iPhone DevicesĪs most iPhone users know, Apple takes a walled-garden approach to app publishing, allowing only approved apps into the App Store. ![]() Apple addressed these concerns in September 2019, stating that the vulnerabilities Google discovered had been exaggerated and were quickly patched once discovered. IPhone security has become a hot topic recently, with Google Security researchers alleging that they discovered major iPhone security flaws that allow the devices to be compromised. Virus Protection for iPhone Do Apple iPhones Need Antivirus Software Read More: What Does Antivirus Software Do? Heuristics is about detecting virus-like behavior or attributes rather than looking for a precise virus signature that matches a signature on the virus blacklist. Files run in Comodo containment are kept in a sandbox environment, separate from your operating system. If suspicious code is detected then the antivirus deletes the file or recommends it for containment. Heuristic detection describes the method of analyzing the code of a file to determine if it contains code commonly found in malware. Modify the code slightly, and the malware is rendered undetectable.Ĭomodo Antivirus also uses heuristic detection and containment to ensure that even unknown malware cannot compromise our users’ computers. Like a wanted outlaw in the old west, a cybercriminal can disguise a piece of malware to avoid detection. This process is executed quickly and is an essential feature of an antivirus software, but it is also easy for cybercriminals to evade. Specific detection works by scanning a file for a specific set of characteristics and checking these characteristics against a known list of malware. This is what most people think of when they think about how an antivirus works. The most basic detection process is known as specific detection. Most modern antivirus programs feature multiple scanning detection processes. Whenever you download or launch a file, an antivirus program scans the file for malware. ![]() ![]() ![]() These are so great to add to your weekly meal prep as well.Īlso, we have another list of go-to menu items if you are looking for fast food options. ![]() Remember, a lot of these, if not all, can be adjusted easily to fit your macros without changing the deliciousness of the recipe. In each description I am including the macros. I’ve compiled a list for you to hopefully make this journey easier. Well, I could easily add a 3rd ounce to better hit my protein goal.īut, if the recipe was something like chili, that’s a little harder to adjust and harder to track accurately. Micronutrients are another essential part of human nutrition and consist of. So to be considered “macro friendly,” a recipe should be pretty high in protein, with a moderate amount of fat & carbs.Īnother factor to consider is how easily the recipe can be adjusted to hit your own specific macro nutrient goals.įor example, say I’m eating a salad & it only calls for 2 ounces of chicken on top. In this calculator, we only calculate daily carbohydrate, protein, and fat needs. Carbs will vary based on whether you are cutting, bulking, or maintaining. Also, most people have only around 30% of their intake come from fats. Most people have the hardest time hitting protein. While everyone’s macros are different, there are some similarities. ![]() What are considered macro friendly recipes? But, that being said there are definitely certain meals that make tracking easier. Your numbers are customized to your height, weight, and activity level. These macro recipes for weight loss are perfect for those counting macros or following a IIFYM lifestyle. Why? Because with IIFYM there is no one size fits all meal plan. Janushares Last Updated on Januby Rachel Macro friendly dinner recipes that are high in protein and low to moderate in fat and carbs. Sweet Potato And Black Bean Quinoa BowlsPaleo Breakfast BowlsLemon Chicken With VeggiesEgg White Scramble And Sweet Potato HashCold Sesame Noodle BowlsSpring Roll Bowls With Almond. People are always asking for easy meal plans to follow, but the truth is it wouldn’t work. The hardest thing about counting macros is figuring out what to eat. I can’t wait to support you on your healthy living journey.Macro Friendly Recipes that are high protein & perfect to incorporate into your new IIFYM lifestyle. ![]() Whether you’re counting macros and living a carb-cycling lifestyle, a busy mama who needs new ideas for healthy recipes or a girl who just wants to know what the heck to eat to reach your health and fitness goals MMP has you covered. I believe so strongly in the power of real food and my goal is to make it simple to put a healthy meal on the table without the stress. To make it easy for you to know exactly how to eat, to help you effortlessly create your meal plan in minutes so you can easily shop and go into each week confident and empowered. I created Macro Meals Planned as a tool for YOU. Try recipes like Shrimp Cauliflower Fried Rice and Lemon-Garlic Chicken with Green Beans for a satisfying and quick dinner you'll want to make again and again. They're also low in carbohydrates and packed with vegetables. Click here to add Chicken, Rice & Broccoli to your client’s That Clean Life meal plan. Whether it's chicken, shrimp or pork, these dinners have at least 15 grams of protein. It has 12g of fat, 41g of carbs, and 31g of protein per serving. I completely understand how hard it can be to know what to eat when you’re trying to live a healthier lifestyle and how challenging it is to get dinner on the table as a busy woman balancing a million things. Chicken, Rice & Broccoli With just six ingredients, this recipe is a classic way to teach your clients how to balance their plates. Hello and welcome! I’m Kate, healthy living chef, author, entrepreneur, and girl on a mission to empower busy women to simplify what the heck to cook and eat to reach their goals. ![]() |
AuthorWrite something about yourself. No need to be fancy, just an overview. ArchivesCategories |